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Even if you used a quantitative research design, but failed to employ a probability sampling technique, there are still many perfectly justifiable reasons why you could have made such a choice. For example, it may have been impossible (or near on impossible) to get a list of the population you were studying (., a list of all the 20,000 students at the single university you were interested in). Since probability sampling is only possible when we have such a list, the lack of such a list or inability to attain such a list is a perfectly justifiable reason for not using a probability sampling technique; even if such a technique is the ideal.